Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt (MLYB): Implications for Mineralization and Exploration     

NIE Liqing  ZHOU Taof  CHEN Xuefeng  WANG Fangyue  XIAO Xin 《《地质学报》英文版》2020,94(6):1977-1996

The Middle–Lower Yangtze River Metallogenic Belt (MLYB) is known to contain abundant copper and iron porphyry-skarn deposits, with an increasing number of tungsten deposits and scheelite in Fe–Cu deposits being discovered in the MLYB during recent decades. The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood. We investigate four sets of scheelite samples from tungsten, iron and copper deposits, using CL imaging and LA–ICP–MS techniques to reveal internal zonation patterns and trace element compositions. The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies. The oxygen fugacity of ore-forming fluid increased in Donggushan, while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan, Guilinzheng and Gaojiabang. The scheelites from the Donggushan, Ruanjiawan, Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE, with Nb/La ratios ranging from 1.217 to 52.455, indicating that the four tungsten deposits are enriched in the volatile fluorine. A plot of (La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type, porphyry and skarn tungsten deposits. This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.  相似文献   

巢湖杭埠河流域湖相沉积物多指标揭示的全新世以来环境演变     

周慧  吴立  马春梅  管后春  孙小玲  路曙光  尚广春  汪勇  徐仪红  徐军  陈晔  鲍远航 《湖泊科学》2020,32(6):1869-1881

在巢湖杭埠河流域中的古湖盆中心——三河圩区获取28.6 m长的湖相岩芯（SZK1507孔），利用AMS¹⁴C测年技术建立可靠的地层年代序列，通过对SZK1507孔738 cm以上段湖相沉积物平均粒径、磁化率、总氮（TN）、总有机碳（TOC）及C/N的综合分析，高分辨率重建了巢湖杭埠河流域全新世以来的古环境演变过程.结果表明，本区域的环境变化过程可以分为4个阶段，阶段Ⅰ（约10050—9700 cal.a B.P.）与阶段Ⅲ（约9250—5300 cal.a B.P.）气候较为湿润，巢湖水位较高，平均粒径、磁化率值较低，TN、TOC、C/N也偏低；阶段Ⅱ（约9700—9250 cal.a B.P.）与阶段Ⅳ（约5300 cal.a B.P.以来）气候干燥，巢湖水量减少，水位降低，平均粒径、磁化率值、TN、TOC、C/N均较高.一些全球范围内显著发生的气候突变事件在SZK1507孔沉积记录中也有体现，如9.3、8.2和4.2 ka B.P.事件等.将巢湖杭埠河流域10000 cal.a B.P.以来的平均粒径、磁化率、TN、TOC、C/N沉积记录与全新世以来的北纬30°夏季太阳辐射量、太阳黑子数、火山喷发对大气中硫酸盐含量贡献率等进行对比，发现巢湖杭埠河流域全新世气候突变事件主要受控于北半球夏季太阳辐射量变化、太阳活动以及火山活动等因素，并与它们之间复杂的响应机制有关.  相似文献   

珠江口盆地荔湾凹陷上渐新统—早中新统物源特征及其对沉积充填的影响     

邢作昌  张忠涛  林畅松  张博  洪方浩  张正涛 《中国地质》2020,47(5):1577-1588

利用化学蚀变指数法恢复物源区的风化历史及沉积物通量是一种经济实用、行之有效的方法。前人对珠江口盆地荔湾凹陷对应物源区的研究相对薄弱。本文通过对区内岩心测试数据进行化学蚀变指数分析，恢复晚渐新世—早中新世物源区的风化历史，并进行沉积物通量的估算，在此基础上探讨物源特征对研究区内沉积充填的控制作用。研究表明，晚渐新世研究区对应物源区经历了强烈风化阶段，该阶段产生的丰富的沉积物供给是研究区西北部快速进积、规模壮观的陆架边缘三角洲及斜坡重力流沉积体系发育的重要控制因素之一；早中新世，西北物源区风化减弱，沉积供给减少，但研究区东部沉积物供应较西部要充分得多，表明早中新世，研究区南部除了来自西北部的主要物源外，局部物源对该时期的沉积具有重要影响；推测东部物源(东部古隆起、兴宁古隆起)的突然复活是促进研究区东部早中新世沟槽形成发育的重要原因之一。在超深水区进行沉积物源区的研究中，这种半定量的方法对盆内局部物源的确定具有重要的指示意义。  相似文献   

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

Early Jurassic palaeoenvironments in the Surat Basin,Australia – marine incursion into eastern Gondwana     

Andrew D. La Croix  Jianhua He  Valeria Bianchi  Jiahao Wang  Sebastian Gonzalez  Jim R. Undershultz 《Sedimentology》2020,67(1):457-485

Interpretations of palaeodepositional environments are important for reconstructing Earth history. Only a few maps showing the Jurassic depositional environments in eastern Australia currently exist. Consequently, a detailed understanding of the setting of Australia in Gondwana is lacking. Core, wireline logs, two-dimensional and three-dimensional seismic from the Precipice Sandstone and Evergreen Formation in the Surat Basin have been used to construct maps showing the evolution of depositional environments through the Early Jurassic. The results indicate the succession consists of three third-order sequences (Sequence 1 to Sequence 3) that were controlled by eustatic sea level. The lowstand systems tract in Sequence 1 comprises braidplain deposits, confined to a fairway that parallels the basin centre. The strata were initially deposited in two sub-basins, with rivers flowing in different orientations in each sub-basin. The transgressive systems tract of Sequence 1 to lowstand systems tract of Sequence 3 is dominated by fluvio–deltaic systems infilling a single merged basin centre. Finally, the transgressive and highstand systems tracts of Sequence 3 show nearshore environments depositing sediment into a shallow marine basin. In the youngest part of this interval, ironstone shoals are the most conspicuous facies, the thickness and number of which increase towards the north and east. This study interprets a corridor to the open ocean through the Clarence–Moreton Basin, or the Carpentaria and Papuan basins, evidence of which has been eroded. These results challenge a commonly held view that eastern Australia was not influenced by eustasy, and propose a more dynamic palaeogeographic setting comprising a mixture of fluvial, deltaic and shallow marine sedimentary environments. This work can be used to unravel the stratigraphic relationships between Mesozoic eastern Australian basins, or in other basins globally as an analogue for understanding the complex interplay of paralic depositional systems in data poor areas.  相似文献   

Sedimentary and geochemical characterization of Middle–Late Miocene formations in the Neogene Tsugaru Basin,Japan by means of DTH27‐1 well sediment analysis     

Paolo Martizzi  Shun Chiyonobu  Hiroyuki Arato 《Island Arc》2020,29(1)

Middle–Late Miocene age siliceous formations outcropping along the northwestern side of Honshu Island are considered prospective source rocks for hydrocarbons. An analysis of geophysical, sedimentological, and geochemical properties is essential to evaluate the formations' source potential, and to understand the factors that determined the accumulation and preservation of organic matter. This study investigates the Middle–Late Miocene geological record of the Tsugaru back‐arc basin, located in the western part of Aomori prefecture, through an analysis of a 200 m long portion of a core from the DTH27‐1 well; this core is composed of the diatomaceous siltstones of the Akaishi Formation and the siliceous mudstones of the Odoji Formation. Sedimentological and geophysical characterization showed that the Akaishi Formation's diatomaceous siltstones are mostly massive and bioturbated, have low magnetic susceptibility, and demonstrate moderate natural radioactivity. Although the Odoji Formation's siliceous mudstones are massive, they have exceedingly low magnetic susceptibility and high natural radioactivity. Geochemical data from a Rock‐Eval Pyrolysis such as total organic carbon and generative potential (S1 + S2) revealed that, in the Tsugaru area, only the Odoji Formation is a likely prospective source rock for hydrocarbons. On the other hand, T_max values indicate that both the formations are thermally immature for generating hydrocarbons. The difference between the Akaishi and Odoji Formation in the sedimentological facies, in terms of the degree of bioturbation and the organic carbon content, indicates variations in lithological properties, such as porosity and grain size; moreover, this difference indicates a variation in the paleo‐oxygenation of bottom waters, with the transition from oxygen‐deficient conditions in the Middle Miocene to the more oxygenated conditions in the Late Miocene. Both the lithological and paleo‐environmental factors possibly influenced the organic richness in the two formations.  相似文献   

Terraces Development and Their Implications for Valley Evolution of the Jinsha River Since Late Pleistocene near Longjie,Yunnan     

Fenliang Liu  Hongshan Gao  Zongmeng Li  Baotian Pan  Huai Su 《地球科学进展》2020,35(4):431-440

The drainage evolution and valley development of the Jinsha River is an important issue constantly concerned by researchers in geology and geomorphology. Despite hundreds of years of research, there is a big dispute on the formation time and the evolution process of the fluvial valley. Fluvial terraces are very important geomorphic markers for studying the formation and evolution of the fluvial valley. Through field investigation combined with Electron Spin Resonance (ESR) dating, we confirmed that 5 fluvial terraces were formed, and then preserved, along the course of the Jinsha River near the Longjie, which are all strath terraces. Among them, T5 developed on the base rock, with an age of (78±12) ka; all T4~T1 developed on the lacustrine sediments, named Longjie Group by Chinese, with an age of (29±1.4) ka, (26±2.4) ka, (23±1.4) ka, (18±1.7) ka, respectively. Compared with the global and regional climate change history, the terraces are all the result of the river responding to the climate change. T5 formed at MIS 5/4, and T4~T1 formed at the period of regional climate fluctuation. The relationship of terraces and the Longjie Formation, combined with sedimentary characteristics analysis demonstrate that the Longjie Formation is landslide dammed lake sediment. The landslide and blocking events.seriously influenced the valley evolution, inhibiting the river incising, and making the valley evolution defer to the mode of “cut-landside-damming-fill-cut” in the period of Late Pleistocene. Synthesized studies of the terraces and the correlative sediments indicate that the formation of the Jinsha River valley may have begun in the late Early Pleistocene.  相似文献   

天山南坡高冰川覆盖率的木扎提河流域水文过程对气候变化的响应   总被引：5，自引：5，他引：0  

赵求东  赵传成  秦艳  苌亚平  王建 《冰川冻土》2020,42(4):1285-1298

木扎提河是天山南坡冰川面积覆盖率最大（48.2%）的河流， 流域径流过程对气候变化极为敏感， 为了合理管理和规划水资源， 确保水资源的可持续利用， 亟需定量评估气候变化对该流域水文过程的影响。以VIC-CAS分布式水文模型为计算平台， 利用实测的径流和两次冰川编目间的冰川面积变化数据开展了模型的多目标参数化校正和验证， 有效提高了模拟结果的“真实性”， 然后通过数值模拟结果结合观测数据定量解析了流域径流的组成、 变化特征及对气候变化的响应机理。结果表明： 木扎提河总径流集中在暖季（5 - 9月）， 占全年总径流量的77.9%， 冰川径流、 融雪径流和降雨径流分别占总径流量的66.6%、 26.4%和7.0%。1971 - 2010年木扎提河流域气温和降水呈显著增加趋势， 由于降水的增加， 降雨和融雪径流均呈增加趋势， 但冰川径流呈现明显减少趋势， 导致总径流呈现下降趋势。在RCP4.5情景下， 未来该流域气温呈现明显升高趋势， 降水表现为微弱下降趋势； 气候变暖后， 更多降水以降雨形式发生， 未来降雨径流将明显增加， 降雪和融雪径流已于20世纪90年代达到峰值， 随后明显减少； 冰川面积将持续萎缩， 冰川径流于21世纪10年代达到拐点， 随后明显减少， 导致河道总径流量也将明显减少。  相似文献   

青海共和盆地地热流体地球化学特征及热储水-岩相互作用过程     

马月花  唐保春  苏生云  张盛生  李成英 《地学前缘》2020,27(1):123-133

地热流体地球化学组成及其运移规律和成因机制研究对地热资源勘查和开发利用具有重要意义。当前,青海省地热资源开发利用程度低,更缺乏针对地热流体地球化学特征进行深入研究的系统性工作。青海共和盆地是青藏高原北缘的一个断陷盆地,盆地内地热资源丰富。本文以共和盆地及周围部分山区的地热系统为研究对象,基于系统地球化学采样和测试开展了地热流体地球化学组成及热储水-岩相互作用过程分析,认为:从共和下更新统热储、新近系热储到鄂拉山构造岩浆带再到瓦里贡山构造岩浆带,地热水中SiO₂含量依次升高,反映热储温度依次升高;上述地热地区热储中原生铝硅酸盐矿物的溶解和蚀变矿物的形成是控制地热水中阳离子含量的最重要的水文地球化学过程,而补给水下渗和地热水径流及升流过程中盐类矿物的溶滤则是水中阴离子(特别是 {\mathrm{SO}}_4^{2-}和Cl^-)的主要来源。  相似文献   

文昌B凹陷差异伸展- 走滑机制及控藏作用研究     

江汝锋  周家雄  杨希冰  游君君  李珊珊  陈林  张霞 《地质学报》2020,94(8):2422-2432

为查明文昌B凹陷油气富集差异性的原因，基于断裂展布和形成期次、构造样式组合、构造演化和断层活动的差异等标志，建立了差异伸展- 走滑机制，识别出19洼为伸展- 强走滑、14洼为伸展- 中等走滑、30洼为伸展- 弱走滑。差异伸展- 走滑作用控制了优质烃源岩的展布和供烃方向，控制输导体系类型和运移动力，提供物源通道和改造储层，还控制了圈闭类型和力学性质。进一步深化了走滑增压理论，基于先存断裂形态、伸展应力场右旋演化和应变差异，建立了走滑增压圈闭识别方法，识别出S型增压、右行左阶增压、斜交型增压3种走滑增压构造。研究表明，文昌B凹陷的油气富集受伸展- 走滑构造背景、源- 运时空配置关系所控制，强—中等走滑变形、发育优质中深湖源岩的文昌19洼和14洼是油气富集区。该研究成果成功推动了文昌凹陷近期的多个勘探发现。  相似文献